| 作者简介：BILL CARRUTHERS was born in Glasgow. He won a bursary to Glasgow Uni- versity, where he graduated with a first-class honours degree in 1946 and a Ph.D. in 1949. He moved to Exeter in 1956, working first for the Medical Research Council and then, from 1968, as a lecturer then senior lecturer at the Department of Chemistry in the University of Exeter. He died in April 1990, just a few months before he was due to retire. |
| Preface to the first edition Preface to the fourth edition 1 Formation of carbon-carbon single bonds 1.1 Main-group chemistry 1.1.1 Alkylation of enolates and enamines 1.1.2 Conjugate addition reactions of enolates and enamines 1.1.3 The aldol reaction 1.1.4 Asymmetric methodology with enolates and enamines 1.1.5 Organolithium reagents 1.1.6 Organomagnesium reagents 1.1.7 Organozinc reagents 1.1.8 Allylic organometallics of boron, silicon and tin 1.2 Transition-metal chemistry Problems 1.2.1 Organocopper reagents 1.2.2 Organochromium chemistry 1.2.3 Organocobalt chemistry 1.2.4 Organopalladium chemistry 2 Formation of carbon-carbon double bonds 2.1 B-Elimination reactions 2.2 Pyrolytic syn eliminations 2.3 Fragmentation reactions 2.4 Alkenes from hydrazones 2.5 Alkenes from 1,2-diols 2.6 Alkenes from alkynes 2.7 The Wittig and related reactions 2.8 Alkenes from sulfones 2.9 Alkenes using titanium or chromium reagents 2.10 Alkene metathesis reactions Problems 3 Pericyclic reactions 3.1 The Diels-Alder cycloaddition reaction 3.1.1 The dienophile 3.1.2 The diene 3.1.3 Regiochemistry of the Diels-Alder reaction 3.1.4 Stereochemistry of the Diels-Alder reaction 3.1.5 Intramolecular Diels-Alder reactions 3.1.6 The retro Diels-Alder reaction 3.1.7 Asymmetric Diels-Alder reactions 3.2 [2+2] Cycloaddition reactions 3.3 Cycloaddition reactions with allyl cations and allyl anions 3.4 1,3-Dipolar cycloaddition reactions 3.5 The ene reaction 3.6 [3,3]-Sigmatropic rearrangements 3.6.1 The Cope rearrangement 3.6.2 The Claisen rearrangement 3.7 [2,3]-Sigmatropic rearrangements 3.8 Electrocyclic reactions Problems 4 Radical and carbene chemistry 4.1 Radicals 4.1.1 Radical abstion reactions 4.1.2 Radical addition reactions 4.2 Carbenes Problems 5 Functionalization of alkenes 5.1 Hydroboration 5.1.1 Reactions of organoboranes 5.2 Epoxidation and aziridination 5.2.1 Epoxidation 5.2.2 Asymmetric epoxidation 5.2.3 Aziridination …… 6 Oxidation 7 Reduction Answers to problems Index |
内容加载中，请稍后...
商品评论（0条）