| Series Preface Preface to the Third Edition Preface to the Second Edition Preface to the First Edition Chapter 1 Introduction to Bioorganic Chemistry 1.1 Basic Cansiderations 1.2 Proximity Effects in Organic Chemistry 1.3 Molecular Adaptation 1.4 Molecular Recognition and the Supramolecular Level Chapter 2 Bioorganic Chemistry of Amino Acids and Polypeptides 2.1 Chemistry of the Living Cells 2.2 Analogy Betweel~ Organic Reactions and Biochemical Transformations 2.3 Chemistry of the Peptide Bond 2.4 Nonribosomal Peptide Bond Formation 2.5 Asymmetric Synthesis of a-Amino Acids 2.6 Asymmetric Synthesis with Chiral OrganometaUic Catalysts 2.7 Transition State Analogs 2.8 Antibodies as Enzymes 2.10 Molecular Recognition and Drug Design Chapter 3 Bioorganic Chemistry of the Phosphate Groups and Po[ynuc[eotides 3.1 Basic Considerations 3.2 Energy Storage 3.3 Hydrolytic Pathways and Pseudorotation 3.4 DNA lntercalants Chapter 4 Enzyme Chemistry 4.1 Introduction to Catalysis 4.2 Introduction to Enzymes 4.3 Multifunctional Catalysis and Simple Modeis 4.4 a-Chymotrypsin 4.5 Other Hydrolytic Enzymes 4.6 Stereoelectronic Control in Hydrolytic Reactions 4.7 Immobilized Enzymes and Enzyme Technology 4.8 Enzymes in Synthetic Organic Chemistry 4.9 Enzyme-Analog-Built Polymers 4.10 Design of Molecular Clefts Chapter 5 Enzyme Models 5.1 Host Guest Complexation Chemistry 5.2 New Developments in Crown Ether Chemistry 5.3 Membrane Chenlistry and beliceIles 5.4 Polymers 5.5 CycIodextrins 5.6 Enzyme Design Using Steroid Template 5.7 Remote Functionalizadon Reactions 5.8 Biomimetic Polyene CycIizations Chapter 6 Metar Ions 6.1 Metal Ions in Proteins and Biological MolecuIes 6.2 Carboxypeptidase A and the Role of Zinc 6.3 Hydrolysis of Amino Acid Esters and Amides and Peptides 6.4 Iron and Oxygen Transport 6.5 Copper Ion 6.6 Biomodels of Photosynthesis and Energy Transfer 6.7 Cobalt and Vitamin B,, Action Chapter 7 Conenzyme Chemistry Chapter 8 Molecular Devices References Index |
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