| Foreword to first edition . Foreword to second edition Symbols and abbreviations Mechanistic designations 1 Models of chemical bonding 1.1 Covalency and molecular structure 1.2 Approximate molecular orbital theory 1.3 Properties of covalent bonds 1.4 Intermolecular forces Problems References 2 Kinetics and tbermodynamics 2.1 Enthalpy 2.2 Entropy 2.3 The Gibbs function， G 2.4 Factors that contribute to entropy 2.5 Chemical equilibrium 2.6 Some useful thermodynamic relationships 2.7 The application of thermodynamics to rate processes 2.8 Properties of the transition state 2.9 The uses of activation parameters 2.10 The location of the transition state Problems References 3 Reagents and reaction mecbanisms 3.1 Polar and radical pathways 3.2 A classification of fundamental reaction types 3.3 Reaction mechanism 3.4 Electron supply and demand 3.5 Transition-state properties an structural change Problems References 4 Correlation of sturcture with reactivity 4.1 Electronic demansds 4.2 The Hammett equation 4.3 Substituent constants e 4.4 Theories of substituent effects 4.5 Interpretation of e-values 4.6 Reaction constans,p 4.7 Deviations from the Hammett equation 4.8 Dual-parameter correlations：the fowering of LFER 4.9 Molecular orbiatl considerations 4.10 Cross-interactin terms Problems References 5 Solvent effects 5.1 The structure of liquids 5.2 Solutions 5.3 Solvation …… 6 Acids and bases, electrophiles and nucleopbiles 7 Kinetic isotope effects 8 Steric and conformational properties 9 Homogeneous catalysis 10 Substitution reactions at carbon 11 Elimination reactions 12 Polar addition reactions 13 Intramolecular reactions 14 Pericyclic reactions 15 Reactions via free readicals 16 Organic photobemistry Index |
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