| preface to the first edition . preface to the third edition 1 formation of carbon-carbon single bonds 1.1. alkylation: importance of enolate anions 1.2. alkylation of relatively acidic methylene groups 1.3. γ-alkylation of 1,3-dicarbonyl compounds; dianions in synthesis 1.4. alkylation of ketones 1.5. the enamine and related reactions 1.6. alkylation of a-thio and a-seleno carbanions 1.7. umpolung (dipole inversion) 1.8. the aldol reaction 1.9. allylic alkylation of alkenes 1.10. the dihydro-l,3-oxazine synthesis of aldehydes and ketones 1.11. coupling of organonickel and organocopper complexes 1.12. reactions of lithium organocuprates: copper-cata-lysed reactions of grignard reagents 1.13. synthetic applications of carbenes and carbenoids 1.14. formation of carbon-carbon bonds by addition of free radicals to alkenes 1.15. some photocyclisation reactions 2 formation of carbon-carbon double bonds 2.1. fi-elimination reactions .2.2. pyrolytic syn eliminations 2.3. sulphoxide-sulphenate rearrangement; synthesis of allyl alcohols 2.4. the wittig and related reactions 2.5. alkenes from sulphones 2.6. decarboxylation of β-lactones stereoselective synthesis of tri- and tetra- substituted alkenes 2.8. fragmentation reactions 2.9. oxidative decarboxylation of carboxylic acids 2.10. alkenes from arylsulphonylhydrazones 2.11. stereospecific synthesis from 1,2-diols 2.12. c!aisen rearrangement of allyl vinyl ethers 2.13. reductive dimerisation of carbonyl compounds 3 the diels-a!der and related reactions 3.1. general 3.2. the dienophile - heterodienophiles, oxygen as a dienophile 3.3. the diene - acyclic dienes, heterodienes, 1,2-dimethylenecycloalkanes, vinylcycloalkenes and vinylarenes, aromatic hydrocarbons, cyclic dienes, cyclopentadienones and ortho-quinones, furans 3.4. intramolecular diels-alder reactions 3.5. the retro diels-alder reaction 3.6. catalysis by lewis acids 3.7. regiochemistry of the diels-a!der reaction 3.8. stereochemistry of the diels-alder reaction 3.9. asymmetric diels-alder reactions 3.10. mechanism of the dieis-alder reaction 3.11. photosensitised diels-alder reactions 3.12. the erie reaction 3.13. cyclo-addition reactions with allyi cations and allyl anions 3.14. 1,3-dipolar cyclo-addition reactions 4 reactions at unactivated c—h bonds 4.1. the hoffmann-loeffler-freytag reaction 4.2. cyclisation reactions of nitrenes 4.3. the barton reaction and related processes - photolysis of organic nitrites and hypohalites, photolysis of nnitrosoamides 4.4. reaction of monohydric alcohols with lead tetraacetate .. 4.5. miscellaneous reactions - unsaturated alcohols from hydroperoxides, cyclobutanols by photolysis of ketones, long-range functionalisation of unactivated carbons on the steroid nucleus 5 synthetic applications of organoboranes and organosilanes 5.1. hydroboration 5.2. reactions of organoboranes - protonolysis, oxidation, enantioselective synthesis of secondary alcohols from alkenes, isomerisation and cyclisation of alkylboranes 5.3. formation of carbon-carbon bonds - carbonylation of organoboranes, reaction with α-bromoketones and α-bromoesters, reaction with diazo compounds 5.4. reactions of alkenylboranes and trialkylalkynylborates 5.5. free-radical reactions of organoboranes 5.6. applications of organosilieon compounds in synthesis - protection of functional groups, trimethylsilyl ethers, silyl enol ethers 5.7. alkenylsilanes and allylsilanes 5.8. control of rearrangement of carbonium ions by silicon - the b-effect 5.9. α-silyl carbanions 5.10. β-silylcarbonyl compounds 5.11. trimethylsilyl cyanide 5.12. trimethylsilyl iodide and tfimethylsilyl triflate 6 oxidation 6.1. oxidation of hydrocarbons 6.2. oxidation of alcohols - chromic acid, chromium vi oxide-pyridine complexes, manganeseiv oxide, silver carbonate, oxidation via alkoxysulphonium salts, other methods 6.3. oxidation of carbon-carbon double bonds - diols, epoxides, enantioselective epoxidation of allylic alcohols (sharpless epoxidation), diastereoselective epoxidation of homoallylic alcohols, synthetic reactions of epoxides, ozonolysis 6.4. photosensitised oxidation of alkenes 6.5. palladium-catalysed oxidation of aikenes 6.6. oxidation of ketones - conversion into αβ-unsatur-ated ketones, baeyer-vi!!iger oxidation 6.7. oxidations with ruthenium tetroxide 6.8. oxidations with thallium(iii) nitrate 7 reduction 7.1. catalytic hydrogenation - the catalyst, selectivity of reduction, reduction of functional groups, stereochemistry and mechanism, homogeneous hydrogenation 7.2. reduction by dissolving metals - reduction with metal and acid, reduction of carbonyi compounds, reductions with metal in liquid ammonia (birch reduction), reductive fission of alcohols and halides 7.3. reduction by hydride-transfer reagents - aluminium alkoxides, lithium aluminium hydride and sodium borohydride, lithium hydridoalkoxyaluminates, lithium aluminium hydride-aluminium chloride reagents, di-isobutylaluminium hydride, sodium cyanoborohydride, trialkylborohydrides 7.4. reductions with borane and dialkylboranes 7.5. other methods - woiff-kishner reduction, desui-phurisation of thio-acetals, di-imide, iow-valent titanium species, trialkyltin hydrides, trialkyl-silanes references index ... |
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