
| Liang-Yin Chu Smart Membrane Materials and Systems From Flat Membranes to Microcapsule Membranes. Smart Membrane Materials and Systems From Flat Membranes to Microcapsule Membranes comprehensively and systematically treats modern understanding of smart or intelligent membranes with environmental stimuli-responsive functions. The contents range from flat membranes to microcapsule membranes with various response properties, such as thermo-response, pH-response, glucose-response, molecular-recognition, and dual-/multi-stimuli-response. While chapters may be read as stand-alone, together they clearly describe cover design concepts, fabrication strategies and methods, microstructures and performances of smart membranes. Vivid schematics and illustrations throughout the book enhance accessibility to the theory and technologies. The book is intended for researchers and postgraduate students in membrane science and technology, separations and controlled-release. Dr. Liang-Yin Chu is a professor at the School of Chemical Engineering, Sichuan University, China. He is a Distinguished Young Scholar of the National Natural Science Foundation of China and a Distinguished Professor of "Chang Jiang Scholars Program" of the Ministry of Education of China. |
| 1 Introduction 1.1 A Glance at Membranes and Their Developments 1.2 Environmental Stimuli-Responsive Gating Model of Biomembranes 1.3 Environmental Stimuli-Responsive Smart Materials 1.3.1 Thermo-Responsive Smart Materials 1.3.2 pH-Responsive Smart Materials 1.3.3 Glucose-Responsive Smart Materials 1.3.4 Molecular-Recognizable Smart Materials 1.4 Bio-Inspired Design of Environmental Stimuli-Responsive Smart Membranes 1.4.1 Smart Membranes with Porous Substrates and Stimuli-Responsive Gates 1.4.2 Smart Membranes with Grafted Stimuli-Responsive Surfaces 1.4.3 Stimuli-Responsive Smart Hydrogel Membranes References 2 Thermo-Responsive Gating Membranes: Design, Microstructures and Performances 2.1 Design of Thermo-Responsive Gating Membranes 2.2 Formation and Microstructures of Grafted PNIPAM Polymers in Pore-Filling Type Thermo-Responsive Gating Membranes 2.2.1 Pore-Filling Type Thermo-Responsive Gating Membranes Fabricated by Plasma-Induced Grafting Polymerization 2.2.2 Pore-Filling Type Thermo-Responsive Gating Membranes Fabricated by Atom-Transfer Radical Polymerization 2.3 Effect of the Grafiting Yield on Thermo-Responsive Gating Characteristics of Pore-Filling Type PNIPAM-Grafted Membranes 2.3.1 Substrate Membranes with Regular Straight Pore Microstructures 2.3.2 Substrate Membranes with Irregular Pore Microstructures 2.4 Effect of the Length and Density of Grafted Chains on Thermo-Responsive Gating Characteristics of PNIPAM-Grafted Gating Membranes 2.5 Gating Characteristics of Thermo-Responsive Membranes with Grafted Linear and Cross linked PNIPAM Gates 2.6 Thermo-Responsive Wettability Characteristics of PNIPAM-Grafted Membranes 2.7 Thermo-Responsive Gating Membranes with Controllable Response Temperature 2.8 Membranes with Negatively Thermo-Responsive Gating Characteristics References 3 Smart Microcapsules with Thermo-Responsive Gating Membranes 3.1 Design of Smart Microcapsules with Thermo-Responsive Gating Membranes 3.2 Fabrication and Performance of Thermo-Responsive Microcapsules with Porous Membrane and PNIPAM Gates 3.2.1 Fabrication of Hollow Microcapsules with Porous Membrane 3.2.2 Grafting PNIPAM Gates in the Membrane Pores of Microcapsules 3.2.3 Thermo-Responsive Controlled-Release Characteristics 3.3 Monodispersed Thermo-Responsive Microcapsules with Porous Membrane and PNIPAM Gates 3.3.1 Preparation of Monodispersed Microcapsules with Porous Membrane 3.3.2 Monodispersed Microcapsules with Porous Membrane and Grafted PNIPAM Gates 3.3.3 Thermo-Responsive Controlled-Release Characteristics References 4 Smart Microcapsules with Thermo-Responsive Hydrogel Membranes 4.1 Introduction 4.2 Monodisperse Thermo-Responsive PNIPAM Hollow Microcapsules Prepared with W/O Single Emulsions as Templates …… 5 Thermo-Responsive Membranes for ChiraI Resolution 6 Thermo-Responsive Membranes for Affinity Separation 7 pH-Responsive Gating Membrane Systems with Pumping Effects 8 Smart Microcapsules with pH-Responsive Hydrogel Membranes 9 Glucose-Responsive Gating Membranes 10 Molecular-Recognizable Smart Membranes 11 Dual-/Multi-Stimuli-Responsive Smart Membranes 12 Perspectives on Smart Membrane Materials and Systems Index |
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