
| preface. 1 qualitative description of liquid properties 1.1 three phases of matter: pvt behaviour of pure materials 1.2 melting and lindemann's law 1.3 molecular thermal movements in the liquid phase: brownian motion 1.4 qualitative considerations continued: flow properties of dense liquids 1.5 rigidity of liquids 1.6 surface properties 1.7 water and ice revisited 2 excluded volume, free volume and hard sphere packing 2.1 excluded volume and packing problems 2.2 accessible configuration space 2.3 experiments on random packing models 2.4 origins of method of molecular dynamics 2.5 free-volume approximation 2.6 free volume and entropically driven freezing transition 2.7 building on hard sphere equation of state 2.8 hard-particle fluid equation of state using nearest-neighbour correlations 2.9 free volume revisited in hard sphere fluid 2.10 hard particles in low dimensions .2.11 equation of state of hard-body fluids 2.12 hard sphere fluid in narrow cylindrical pores 3 thermodynamics, equipartition of energy and some scaling properties 3.1 thermodynamic functions for a fluid 3.2 specific heats and compressibilities 3.3 fluctuation phenomena 3.4 clausius-clapeyron equation and melting 3.5 free energy from partition function 3.6 principle of equipartition of energy 3.7 thermodynamic and other properties of hard sphere fluid 3.8 scaling of thermodynamic properties for inverse-power appendix 3.1 analogues of the clausius-clapeyron equation for other phase transitions appendix 3.2 partition function, phase space and configurational integral for inverse power repulsive potentials 4 structure, forces and thermodynamics 4.1 pair distribution function g(r) 4.2 definition of liquid structure factor s(k) 4.3 diffractive scattering from a liquid 4.4 salient features of liquid structure factor 4.5 internal energy and virial equation of state with pair forces 4.6 ornstein-zernike direct correlation function 4.7 thermodynamic consistency and structural theories 4.8 liquid-vapour critical point 4.9 fluids at equilibrium in a porous medium appendix 4.1 inhomogeneous monatomic fluids appendix 4.2 the dieterici equation of state appendix 4.3 force equation and born-green theory of liquid structure 5 diffusion 5.1 background: magnitude of diffusion coefficients in gases 5.2 fick's law and diffusion equation 5.3 solute diffusion at high dilution in water and in non-aqueous solvents 5.4 summary of techniques, including computer simulation, for determining 5.5 velocity autocorrelation function in pure dense liquids 5.6 models of velocity autocorrelation function 6 viscosity 6.1 hydrodynamic variables 6.2 stresses in a newtonian fluid and the navier-stokes equation 6.3 laminar flow and the measurement of shear viscosity 6.4 creeping flow past an obstacle 6.5 vorticity 6.6 models of viscosity 6.7 transverse currents and sound propagation in isothermal conditions 6.8 microscopic density fluctuations and inelastic scattering appendix 6.1 kinetic calculation of shear viscosity for hard spheres 7 heat transport 7.1 fourier's law 7.2 studies of heat conduction by molecular dynamics 7.3 electronic contribution to heat conduction in liquid metals 7.4 thermodynamics with mass motion and entropy production 7.5 the effect of heat flow on sound wave propagation 7.6 binary fluids.. 7.7 superfluid helium appendix 7.1 kinetic theory of thermal and electrical conductivity appendix 7.2 hydrodynamics of superfiuid helium in the two-fluid model 8 chemical short-range order: molten salts and some metal alloys 8.1 classical one-component plasma: static and dynamic screening 8.2 macroscopic properties of molten salts 8.3 structural functions for multicomponent fluids 8.4 coulomb ordering in monohalides and dihalides 8.5 structure of trivalent-metal halides 8.6 transport and dynamics in molten salts 8.7 chemical short-range order in liquid alloys 9 bonds, rings and chains 9.1 outline 9.2 elemental molecular liquids 9.3 orientational pair correlation function from diffraction experiments 12.6 turbulent shear flows 12.7 turbulence in compressible fluids 12.8 turbulent behaviour of non-newtonian fluids appendix 12.1 navier-stokes equation: analogy with maxwell's equations appendix 12.2 series solution of navier-stokes equation 13 liquid-vapour interface 13.1 background and empirical correlations 13.2 definition of a surface and its thermodynamic properties 13.3 phenomenology 13.4 microscopic theories: direct correlation function 13.5 microscopic theories: two-particle distribution function 13.6 interracial dynamics 13.7 interfacial transport and rheology 14 quantum fluids 14.1 ideal fermi and bose gases 14.2 boson fluids 14.3 normal fermion fluids 14.4 bcs superconductivity and superfluidity in fermion fluids 14.5 electron theory of liquid metals 14.6 liquid hydrogen plasmas and the giant planets appendix 14.1 density profiles in the perturbed electron gas references index... |
商品评论(0条)