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| Preface Introduction:Long Flexible Chains Part A STATIC CONFORMATIONS ⅠA Single Chain 1.1 The Notion of an Ideal Chain 1.11 Simple random walks 1.1.2 More general models for laeal cnalns 1.1.3 Ideal chains under externaJ actions 1.1.4 Pair correlations inside an ideal chain 1.1.5 Summary 1.2 A"Real"Chain i na Good Solvent 1.2.1 The main experiments 1.2.2 Numerical data on self-avoiding walks 1.2.3 Correlations inside a swollen COil 1.2.4 Summary 1.3 The Flory Calculation of the Exponent u 1.3.1. Pnnciples 1.3.3 Why is the Fiery method successful9 1.4 Constrained Chains 1.4.1 A chain under traction 1.4.2 Squeezing a real chain in a tube Ⅱ Polymer Metts Ⅱ1.1. Molten Chains Are Ideal Ⅱ1.1 A self-consistent field argument Ⅱ1.2 Screening in dense polymer systems Ⅱ1.3 One long chain among shorter chains Ⅱ1.4 Mixed chains versus segregated chains Ⅱ1.5 Summary Ⅱ.2. Microsopic Studies or correlationss in Melts Ⅱ2.1 Necessity of labeled species Ⅱ2.2 The correlation hole Ⅱ2.3 More general sequences Ⅱ2.4 The correlation hole in two dimensions Ⅱ2.5 Mixtures of labeled and unlabeled chains Ⅱ2.6 Summary Ⅲ Porymer Solutions in Good Solvents Ⅲ.1. The Mean Field Picture {Flory-Huggins) Ⅲ.1.1. Entropy and energy in a lattiee model Ⅲ.1.2 Low concentrations Ⅲ.1.3 Osmotie pressures Ⅲ.1.4 Critique of mean field theory Ⅲ.2. Scaling Laws fur Athermal Solvents Ⅲ.21 The overlap threShold Ⅲ.2.2 The dilule regime Ⅲ.2.3 Semi-dilute solutions Ⅲ.2.4 The correlation length Ⅲ2.5. The norton of blobs Ⅲ2.6 Correlalion functions Ⅲ2.7 Screening in semi-dilute SOlutions Ⅲ.3. Confined Polymer Solutions Ⅲ.3.1 A semi dilute solution in contact with a repulsive wall Ⅲ.3.2 A semi-dilute solutlon in a cylindrical pore Ⅳ Incompatibility and Segregation Ⅴ Polymer Gels Ⅵ Dynamics of a Single Chain Ⅶ Many-Chain Systems :The Respiration Modex Ⅷ Entanglement Effects Ⅸ Self-Consistent Fields and Random Phase Appproximation Ⅹ Relationships between Polymer Statistics and Critical Phenomena Ⅺ An Introduction to Renormalization Group Ideas Author Index Subject Index |
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