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作 者:(美)Kenneth Wark,JR. , Donald E.Richards 著
出 版 社:清华大学出版社
出版时间:2006 年12月
I S B N:730214186X
| Kenneth Wark, Jr. received his B.S. and M.S. degrees in chemical engineering from Purdue University and the University of Illinois, respectively. He joined the faculty of mechanical engineering at Purdue after receiving his Ph.D. degree from that school. In addition to his primary teaching responsibilities in undergraduate and graduate courses in thermodynamics, he has been involved in courses in heat transfer, fluid mechanics, combustion, and de.. << 查看详细 |
| preface. 1 basic concepts and definitions 1-1 the nature of thermodynamics 1-2 dimensions and units 1-3 system, property, and state 1-4 density, specific volume, and specific gravity 1-5 pressure 1-6 the zeroth law and temperature 1-7 problem-solving techniques 1-8 summary problems 2 the first law of thermodynamics 2-1 concepts of work and energy 2-2 the first law of thermodynamics 2-3 a conservation of energy principle for closed systems 2-4 the nature of the energy e 2-5 heat transfer 2-6 expansion and compression work 2-7 elastic spring work 2-8 other quasiequilibrium work interactions .2-9 summary problems 3 properties of n pure, simple compressible substance 3-1 the state postulate and simple systems 3-2 the pvt surface 3-3 the pressure-temperature diagram 3-4 the pressure-specific volume diagram 3-5 the temperature-specific volume diagram 3-6 tables of properties of pure substances 3-7 tabular data and closed-system energy analysis 3-8 the specific heats 3-9 summary 3-10 appendix: fundamentals of partial derivatives problems 4 the ideal gas, corresponding states,and incompressible models 4-1 ideal-gas equation of state 4-2 internal energy, enthalpy, and specific-heat relations for ideal gases 4-3 specific heats of ideal gases 4-4 energy analysis of closed ideal-gas systems 4-5 the compressibility factor and the corresponding states principle 4-6 property relations for incompressible substances 4-7 summary problems 5 control-volume energy analysis 5-1 introduction 5-2 conservation of mass principle for a control volume 5-3 conservation of energy principle for a control volume 5-4 steady-state control-volume energy equations 5-5 comments on problem-solving techniques 5-6 engineering applications involving steady-state control volumes 5-7 introduction to thermodynamic cycles 5-8 transient (unsteady) flow analysis 5-9 summary problems 6 the second law and entropy 6-1 introduction 6-2 heat engines, refrigerators, and heat pumps 6-3 second-law statements 6-4 reversible and irreversible processes 6-5 the second law and entropy--classical presentation 6-5-1 analytical forms of the kelvin-planck statement 6-5-2 general second-law limitations for heat engines 6-5-3 the thermodynamic temperature scale 6-5-4 performance standards for reversible heat engines 6-5-5 theclausius inequality 6-5-6 the entropy function 6-5-7 entropy generation and the closed-system entropy balance 6-6 the second law and entropy--alternate presentation 6-6-1 the second-law postulate 6-6-2 an entropy balance for a closed system 6-6-3 the thermodynamic temperature scale and the camot efficiency 6-6-4 measuring the entropy function 6-6-5 equivalence of the four statements of the second law 6-7 entropy balance for a control volume 6-8 increase in entropy principle for a closed system 6-9 second-law limitations on the performance of heat engines, refrigerators, and heat pumps 6-10 heat transfer and the ts diagram 6-10-1 entropy change for a thermal-energy reservoir 6-10-2 entropy generation associated with heat transfer 6-10-3 loss in work potential associated with heat transfer 6-11 applications 6-12 entropy in terms of randomness and probability 6-13 summary problems 7 evaluation of entropy change and the control-volume entropy balance 7-1 graphical and tabular presentation of entropy data 7-2 the t ds equations for pure, simple compressible substances 7-3 entropy change of an ideal gas 7-4 entropy change of an incompressible substance 7-5 applications of the steady-state entropy balance for a control volume 7-6 steady-flow work relationships 7-7 summary problems 8 some consequences of the second law 8-1 isentropic processes.. 8-2 adiabatic efficiencies of steady-flow devices 8-3 the carnot cycle 8-4 the transient adiabatic-discharge process 8-5 summary problems 9 availability (exergy) and irreversibility 9-1 introduction 9-2 work and entropy production 9-3 availability 9-4 control-volume availability analysis 9-5 second-law efficiency or effectiveness 9-6 summary problems 10 nonreactive ideal-gas mixtures 10-1 composition analysis of gas mixtures 10-2 pvt relationships for ideal-gas mixtures 10-3 internal energy, enthalpy, and entropy for ideal-gas mixtures 10-4 mixing processes involving ideal gases 10-5 properties of an ideal gas-vapor mixture 10-6 the adiabatic-saturation and wet-bulb temperatures 10-7 the psychrometric chart 10-8 air-conditioning processes 10-9 summary problems 11 pvt behavior of real gases and real-gas mixtures 11-1 the virial equation of state 11-2 two-constant equations of state 11-3 other equations of state 11-4 real-gas mixtures 11-5 summary suggested readings and references problems 12 generalized thermodynamic relationships 12-1 fundamentals of partial derivatives 12-2 some fundamental property relations 12-3 generalized relations for changes in entropy, internal energy, and enthalpy 12-4 generalized relations for cp and cv 12-5 vapor pressure and the clapeyron equation 12-6 the joule-thomson coefficient 12-7 generalized thermodynamic charts 12-8 development of property tables 12-9 summary problems 13 chemical reactions 13-1 stoichiometry of reactions 13-2 actual combustion processes 13-3 the enthalpy of formation 13-4 steady-flow energy analysis of reacting mixtures 13-5 adiabatic flame temperature 13-6 constant-volume thermochemical analysis 13-7 enthalpy of reaction and heating values 13-8 second law analysis of reactions 13-9 availability analysis of reacting systems 13-10 fuel cells 13-11 summary problems 14 chemical equilibrium 14-1 introduction 14-2 the gibbs criterion 14-3 equilibrium and the chemical potential 14-4 the chemical potential of an ideal gas 14-5 the equilibrium constants ko and kp 14-6 calculation of ko values 14-7 calculation of equilibrium compositions 14-8 first-law analysis of equilibrium ideal-gas mixtures 14-9 the van't hoff equation relating ko and δhr 14-10 simultaneous reactions 14-11 summary problems 17 refrigeration systems 17-1 the reversed camot cycle 17-2 the vapor-compression refrigeration cycle 17-3 heat pumps 17-4 cascade and multistaged vapor-compression systems 17-5 liquefaction and solidification of gases 17-6 gas refrigeration cycles 17-7 stifling refrigeration cycle 17-8 absorption refrigeration 17-9 availability analysis of a vapor-compression refrigeration cycle 17-10 summary problems bibliography a-1 supplementary tables and figures (si units) a-2 supplementary tables and figures (uscs units) a-3 introduction to ees symbols selected problem answers photo credits index... |
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