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| 0. opening remarks, .1 1. a chemist's view of group theory, 5 1-1. introduction, 5 1-2. symmetry operations and molecules, 6 1-3. groups, 10 1-4. point groups, 14 1-5. classification of molecules into point groups, 29 1-6. matrix representation of symmetry operations, 35 1-7. characters and character tables, 47 1-8. decomposition of reducible representations and the direct product, 55 additional problems, 58 related reading, 61 2. a skirmish with quantum mechanics, 62 2-1. introduction, 62 2-2. light, 62 2-3. the postulates of quantum mechanics, 68 2-4. some simple illustrations from quantum mechanics, 80 related reading, 92 3. vibrational spectroscopy, 93 3-1. introduction, 93 .3-2. infrared and raman spectra, 93 3-3. diatomic molecules, 100 3-4. transitions between stationary states, 130 3-5. the normal modes of vibration of polyatomic molecules, 135 3-6. selection rules and polarization, 151 3-7. symmetry coordinates and normal modes, 170 3-8. stretching mode analysis, 186 3-9. assignment of real spectra, 190 3-10. the resonance raman effect, 198 3-11. functional group analysis, 201 additional problems, 217 related reading, ..224 4. molecular orbital theory, 225 4-1. introduction, 225 4-2. atoms, 225 4-3. photoelectron spectroscopy, 242 4-4. the lcao molecular orbital method, 245 4-5. diatomic molecules, 253 4-6. polyatomic molecules, 267 4-7. the hfickel method, 288 4-8. transition metal complexes, 299 additional problems, 302 related reading, 306 5. electronic spectroscopy, 307 5-1. introduction, 307 5-2. another look at molecular vibrations, 307 5-3. basic notions, 310 5-4. selection rules, 330 5-5. the electronic spectra of some diatomic molecules, 343 5-6. the fate of absorbed energy, 357 5-7. single bonds, double bonds, and lone pairs, 368 5-8. vibronic analysis, 381 5-9. transition metal complexes, 395 5-10. concluding remarks, 411 additional problems, 412 related reading, 418 appendices a. character tables, 421 b. direct products, 479 c. overtones of degenerate vibrations, 492 d. the shapes of atomic orbitals, 495 e. physical constants, 497 f. energy conversions, 498 g. answers to problems, 499 index, ...543 |
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